Ba’zi 3D-metallarining 2-amino-5-alliltio-1,3,4-tiadiazol bilan kompleks birikmalarini oʻrganish
DOI:
https://doi.org/10.5281/zenodo.17391135Ключевые слова:
1,3,4-tiadiazol, kompleks birikmalar, 3d-metallar, koordinatsion kimyo, IQ-spektroskopiya, termik tahlil.Аннотация
Ushbu maqolada 2-amino-5-alliltio-1,3,4-tiadiazolning Cu(II), Co(II), Ni(II) va Zn(II) xloridlari bilan kompleks
birikmalarini sintez qilish hamda ularning fizik-kimyoviy xossalarini oʻrganish natijalari keltirilgan. Kompleks birikmalar
suvli-spirtli muhitda sintez qilingan va IQ-, UB-spektroskopiya, termogravimetrik tahlil, magnit o‘lchovlar hamda
SEM-EDA tahlili yordamida tavsiflangan. Ligandning koordinatsion markaz bilan bogʻlanish shakli va komplekslarning
tuzilishi aniqlangan. Tadqiqot natijalari shuni koʻrsatdiki, ligand azot va oltingugurt atomlari orqali metall ionlari bilan koordinatsiyalanadi.
Olingan kompleks birikmalarning biologik faolligi va amaliy ahamiyati muhokama qilingan
Библиографические ссылки
1. Parmar K. C., Umrigar N. H. Biological Activity // Journal of Chemical and Pharmaceutical Research. – 2017. – V. 9.
– № 6. – P. 202–214.
2. Shia J. S., Ibrahim M. S., Al-Darraji A. S. Various Chemical and Pharmacological Applications of 1,3,4-Thiadiazole
and Its Derivatives // South Asian Research Journal of Pharmaceutical Sciences. – 2023. – V. 5. – № 6. – P. 240–248.
3. Dol R., Vemulapalli S., Azeez O., Dudding T. A Catalytic One-Pot Synthesis of Sydnone Heterocycles with Mechanistic
Insights // Tetrahedron. – 2023. – V. 148. – P. 133704.
4. Zarei M. One-Pot Synthesis of 1,3,4-Thiadiazoles Using Vilsmeier Reagent as a Versatile Cyclodehydration Agent //
Tetrahedron. – 2017. – V. 73. – № 14. – P. 1867–1872.
5. Wang C., Yamashita M., Hu B., Zhou Y., Wang J., Wu J., Zhang Q. Synthesis, Characterization, and Memory Performance
of Two Phenazine/Triphenylamine-Based Organic Small Molecules through Donor-Acceptor Design // Asian
Journal of Organic Chemistry. – 2015. – V. 4. – № 7. – P. 646–651.
6. Al-Budeiri M. S. H. Review of Electroplating-Plasma Modification Methods for the Production of Anodized Coatings on
Aluminum Alloys: Microstructure, Properties and Application // Bulletin of PNRPU. Mechanical Engineering, Materials
Science. – 2020. – V. 22. – № 3. – P. 51–59.
7. Atashov A., Azamova M., Ziyatov D., Uzakbergenova Z., Torambetov B., Holczbauer T., Kadirova S. Synthesis, Crystal
Structure and Hirshfeld Surface Analysis of Bromidotetrakis [5-(Prop-2-en-1-ylsulfanyl)-1,3,4-thiadiazol-2-amine-κN3]
Copper (II) Bromide // Acta Crystallographica Section E. – 2024. – V. 80. – № 4. – P. 408–412.
8. Aliabadi A. 1,3,4-Thiadiazole-Based Anticancer Agents // Anti-Cancer Agents in Medicinal Chemistry (Formerly Current
Medicinal Chemistry – Anti-Cancer Agents). – 2016. – V. 16. – № 10. – P. 1301–1314.
9. Janowska S., Khylyuk D., Bielawska A., Szymanowska A., Gornowicz A., Bielawski K., Wujec M. New 1,3,4-Thiadiazole
Derivatives with Anticancer Activity // Molecules. – 2022. – V. 27. – № 6. – P. 1814.
10. Martínez-Calvo M., Mascareñas J. L. Organometallic Catalysis in Biological Media and Living Settings // Coordination
Chemistry Reviews. – 2018. – V. 359. – P. 57–79.
Загрузки
Опубликован
Выпуск
Раздел
Лицензия
Copyright (c) 2025 MAKTABGACHA VA MAKTAB TA’LIMI JURNALI
Это произведение доступно по лицензии Creative Commons «Attribution» («Атрибуция») 4.0 Всемирная.
